Low-iridium PEM electrolysis

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Subjects: Energy systems · Chemical engineering

Collections: Energy and materials · Hydrogen production

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The problem

Electricity can split water into hydrogen and oxygen. In a PEM electrolyser, a thin membrane separates the reactions, and an iridium catalyst helps make oxygen. Iridium is scarce. Can these devices use much less of it and still make hydrogen efficiently for years, including when the power rises and falls?[1] [2]

Scope

Low-iridium proton-exchange-membrane water electrolysers meeting current, efficiency and lifetime requirements together under practical variable-power operation, beyond small-cell catalyst tests.

What remains open

Reducing the metal is not enough: the device must also retain its output and efficiency during long operation. Successful small-cell tests leave the combined low-metal, large-device and changing-power challenge open.[1] [2]

Why it matters

Each device uses only a little iridium, but building many devices adds up. Reducing the amount needed without shortening their lives could let more hydrogen-producing equipment be built from a limited metal supply.[2]

Definitions

3 terms
PEM

Proton exchange membrane: a membrane that conducts positively charged hydrogen ions while separating the two sides of this water electrolyser.[1] [2]

catalyst

A material that helps a chemical reaction proceed. Here an iridium-based catalyst helps produce oxygen at the anode; it can still deteriorate during device operation.[1] [2]

iridium loading

The amount of iridium used per unit of electrode area. Lower loading measures metal use; it does not by itself establish efficiency or service life.[1] [2]

Sources

  1. Single-faceted IrO2 monolayer enabling high-performing proton exchange membrane water electrolysis beyond 10,000 h stability at 1.5 A cm−2 Deren Yang and colleagues · 2025-08-06
    Notes on Single-faceted IrO2 monolayer enabling high-performing proton exchange membrane water electrolysis beyond 10,000 h stability at 1.5 A cm−2

    Header6August2025/Abstract/Introduction; Results/Fig7: separately loaded steady and fluctuating tests; Methods: PEM assembly and simulated voltage cycling. Small PEM single cells with distinct steady/fluctuating/loading conditions. Abstract10000h and1000h are not a combined low-loading large-stack lifetime; no industrial-life claim or catalyst proof/measurement replication. Different manuscript area/flow descriptions are not combined into one condition.

  2. Resolving the iridium dilemma in PEM water electrolysis: multiscale design of low-iridium and iridium-free anodes Huihui Li, Jun Xu and Chuan Zhao · 2026-09-16
    Notes on Resolving the iridium dilemma in PEM water electrolysis: multiscale design of low-iridium and iridium-free anodes

    PubMed first-online16September2026 metadata; Abstract: scarcity,acidicOER,activity/durability/transport/device coupling. Review Abstract only,not complete paper read. No guaranteed metal-saving benefit,price estimate or every-electrolysis-type claim.

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